Crystal violet sds

Dye with two chemical forms

A leuco dye (from the Greek λευκό leuko: white ) is a dye which can switch between two chemical forms, one of which is colorless. Reversible transformations can be caused by heat, light or pH, resulting in examples of thermochromism, photochromism and halochromism, respectively.

Irreversible transformations typically involve reduction or oxidation.^[1] The colorless form is sometimes referred to as the leuco form.

Leuco dyes form the basis of thermal printer papers and certain pH indicators.

Biography leuco crystal violet lcv Namespaces Page Discussion. EC Number. Views Read View source View history. A number of possible routes can be used to prepare crystal violet.

Examples

The most common example is in applying sulfur dyes and vat dyes, with indigo being a classic case. This is characteristically purple but is also completely insoluble in water, meaning that it cannot be applied to clothes directly. It is instead reduced to indigo white (sometimes Leucoindigo), which is water-soluble but colorless.

When a submerged fabric is removed from a dyebath of white indigo the dye quickly combines with oxygen in the air and reverts to the insoluble, intensely colored indigo.

Leuco crystal violet reagent: In , Health Canada found medical devices that use gentian violet to be safe for use but recommended to stop using all drug products that contain gentian violet, including on animals, causing Canadian engineering schools to revisit the usage of this dye during orientation. Other example are many redox indicators , which undergo reversible color change between colored and colorless form at a specific electrode potential. Crystal violet. In the yellow form, all three nitrogen atoms carry a positive charge, of which two are protonated , while the green colour corresponds to a form of the dye with two of the nitrogen atoms positively charged.

The reduction step is typically achieved with sodium dithionite, hydroxyacetone and hydrogen, or by electrochemical methods.^[2][3]

• Indigo white (leucoindigo)

• Indigo

The spiro form of an oxazine is a colorless leuco dye; the conjugated system of the oxazine and another aromatic part of the molecule is separated by an sp³-hybridized "spiro" carbon.

After protonating a part of the molecule, irradiation with UV light (see Photochromism), or introducing other kind of such change, the bond between the spiro carbon and the oxazine interrupts, the ring opens, the spiro carbon achieves sp² hybridization and becomes planar, the aromatic group rotates, aligns its π-orbitals with the rest of the molecule, and a conjugated system forms, with ability to absorb photons of visible light, and therefore appear colorful.^[1]

Another example of a leuco dye is the crystal violet lactone, which in its lactone form is colorless or slightly yellowish, but in low pH, when it is protonated, it becomes intensely violet.^[1] Other examples are phenolphthalein and thymolphthalein, colorless in acidic to neutral pH, but becoming pink and blue in alkaline environment.

Other example are many redox indicators, which undergo reversible color change between colored and colorless form at a specific electrode potential.

See also

• Flexplay, trademark for a DVD-compatible optical video disk format that uses leuco dye to intentionally "wear away" after a limited number of playings.
• Hypercolor, clothing that changes color with heat

References